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Issue 31, 2006
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The 6-amino-6-methyl-1,4-diazepine group as an ancillary ligand framework for neutral and cationic scandium and yttrium alkyls

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Abstract

The 6-amino-6-methyl-1,4-diazepine framework is a readily available neutral 6-electron ligand moiety, suitable to support cationic group 3 metal alkyl catalysts; it also provides convenient access to tri- and tetradentate monoanionic ligand derivatives.

Graphical abstract: The 6-amino-6-methyl-1,4-diazepine group as an ancillary ligand framework for neutral and cationic scandium and yttrium alkyls

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Supplementary files

Article information


Submitted
05 May 2006
Accepted
09 Jun 2006
First published
27 Jun 2006

Chem. Commun., 2006, 3320-3322
Article type
Communication

The 6-amino-6-methyl-1,4-diazepine group as an ancillary ligand framework for neutral and cationic scandium and yttrium alkyls

S. Ge, S. Bambirra, A. Meetsma and B. Hessen, Chem. Commun., 2006, 3320
DOI: 10.1039/B606384E

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