Issue 31, 2006
From the journal:

Chemical Communications

The 6-amino-6-methyl-1,4-diazepine group as an ancillary ligand framework for neutral and cationic scandium and yttrium alkyls†

Shaozhong Ge,a   Sérgio Bambirra,a   Auke Meetsmaa  and  Bart Hessen*a  

* Corresponding authors

a Centre for Catalytic Olefin Polymerization, Stratingh Institute of Chemistry and Chemical Engineering, University of Groningen, Nijenborgh 4, Groningen, The Netherlands
E-mail: B.Hessen@rug.nl

Abstract

The 6-amino-6-methyl-1,4-diazepine framework is a readily available neutral 6-electron ligand moiety, suitable to support cationic group 3 metal alkyl catalysts; it also provides convenient access to tri- and tetradentate monoanionic ligand derivatives.

Graphical abstract: The 6-amino-6-methyl-1,4-diazepine group as an ancillary ligand framework for neutral and cationic scandium and yttrium alkyls

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Article information

DOI
https://doi.org/10.1039/B606384E
Article type
Communication
Submitted
05 May 2006
Accepted
09 Jun 2006
First published
27 Jun 2006

Chem. Commun., 2006, 3320-3322

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The 6-amino-6-methyl-1,4-diazepine group as an ancillary ligand framework for neutral and cationic scandium and yttrium alkyls

S. Ge, S. Bambirra, A. Meetsma and B. Hessen, Chem. Commun., 2006, 3320 DOI: 10.1039/B606384E

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