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Issue 34, 2006
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Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes

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Abstract

A rhodium/binap complex has been found to effectively catalyze the isomerization of unactivated internal alkynes to the corresponding 1,3-dienes in the presence of an azomethine imine as the reaction promoter.

Graphical abstract: Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes

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Supplementary files

Article information


Submitted
13 Apr 2006
Accepted
21 Jul 2006
First published
02 Aug 2006

Chem. Commun., 2006, 3646-3647
Article type
Communication

Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes

R. Shintani, W. Duan, S. Park and T. Hayashi, Chem. Commun., 2006, 3646
DOI: 10.1039/B605368H

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