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Issue 28, 2006
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Mulliken–Hush analysis of a bis(triarylamine) mixed-valence system with a N⋯N distance of 28.7 Å

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Abstract

An organic mixed valence compound with a spacer length of 25 unsaturated bonds separating two amine redox centres was synthesised and the electron transfer behaviour was investigated in the context of a Mulliken–Hush analysis in order to estimate the longest redox centre separation for which an intervalence charge transfer band can be observed.

Graphical abstract: Mulliken–Hush analysis of a bis(triarylamine) mixed-valence system with a N⋯N distance of 28.7 Å

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Publication details

The article was received on 30 Mar 2006, accepted on 22 May 2006 and first published on 13 Jun 2006


Article type: Communication
DOI: 10.1039/B604603G
Chem. Commun., 2006, 2959-2961

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    Mulliken–Hush analysis of a bis(triarylamine) mixed-valence system with a N⋯N distance of 28.7 Å

    A. Heckmann, S. Amthor and C. Lambert, Chem. Commun., 2006, 2959
    DOI: 10.1039/B604603G

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