Issue 28, 2006
From the journal:

Chemical Communications

Mulliken–Hush analysis of a bis(triarylamine) mixed-valence system with a N⋯N distance of 28.7 ņ

Alexander Heckmann,a   Stephan Amthora  and  Christoph Lambert*a  

* Corresponding authors

a Institute of Organic Chemistry, University of Würzburg, Am Hubland, Germany
E-mail: lambert@chemie.uni-wuerzburg.de
Fax: +49 931 888 4606
Tel: +49 931 888 5318

Abstract

An organic mixed valence compound with a spacer length of 25 unsaturated bonds separating two amine redox centres was synthesised and the electron transfer behaviour was investigated in the context of a Mulliken–Hush analysis in order to estimate the longest redox centre separation for which an intervalence charge transfer band can be observed.

Graphical abstract: Mulliken–Hush analysis of a bis(triarylamine) mixed-valence system with a N⋯N distance of 28.7 Å

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Article information

DOI
https://doi.org/10.1039/B604603G
Article type
Communication
Submitted
30 Mar 2006
Accepted
22 May 2006
First published
13 Jun 2006

Chem. Commun., 2006, 2959-2961

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Mulliken–Hush analysis of a bis(triarylamine) mixed-valence system with a N⋯N distance of 28.7 Å

A. Heckmann, S. Amthor and C. Lambert, Chem. Commun., 2006, 2959 DOI: 10.1039/B604603G

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