Issue 17, 2006
From the journal:

Chemical Communications

Enantioselective synthesis mediated by chiral crystal of achiral hippuric acid in conjunction with asymmetric autocatalysis

Tsuneomi Kawasaki,a   Kenta Suzuki,a   Kunihiko Hatase,a   Masanari Otsuka,b   Hideko Koshimab  and  Kenso Soai*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, Japan
E-mail: soai@rs.kagu.tus.ac.jp
Fax: +81-3-5261-4631

b Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama, Ehime, Japan

Abstract

Enantiomorphous crystals composed of achiral hippuric acid, i.e., naturally occurring N-benzoylglycine, have been used successfully as chiral inducers in enantioselective synthesis in combination with asymmetric autocatalysis to afford the product with extremely high enantiomeric excess.

Graphical abstract: Enantioselective synthesis mediated by chiral crystal of achiral hippuric acid in conjunction with asymmetric autocatalysis

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Article information

DOI
https://doi.org/10.1039/B602442D
Article type
Communication
Submitted
17 Feb 2006
Accepted
07 Mar 2006
First published
21 Mar 2006

Chem. Commun., 2006, 1869-1871

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Enantioselective synthesis mediated by chiral crystal of achiral hippuric acid in conjunction with asymmetric autocatalysis

T. Kawasaki, K. Suzuki, K. Hatase, M. Otsuka, H. Koshima and K. Soai, Chem. Commun., 2006, 1869 DOI: 10.1039/B602442D

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