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Issue 19, 2006
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The cationic cluster Grignard [{MgCl(thf)2}33-C3H5)2]+

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The synthesis and structure of [{MgCl(thf)2}33-C3H5)2]2[Mg(C3H5)4], which contains both a cationic cluster Grignard and a tetraorganomagnesiate dianion, are reported.

Graphical abstract: The cationic cluster Grignard [{MgCl(thf)2}3(μ3-C3H5)2]+

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Publication details

The article was received on 13 Feb 2006, accepted on 31 Mar 2006 and first published on 11 Apr 2006

Article type: Communication
DOI: 10.1039/B602059C
Citation: Chem. Commun., 2006,0, 2039-2041
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    The cationic cluster Grignard [{MgCl(thf)2}33-C3H5)2]+

    R. A. Layfield, T. H. Bullock, F. García, S. M. Humphrey and P. Schüler, Chem. Commun., 2006, 0, 2039
    DOI: 10.1039/B602059C

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