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Issue 19, 2006
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The cationic cluster Grignard [{MgCl(thf)2}33-C3H5)2]+

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Abstract

The synthesis and structure of [{MgCl(thf)2}33-C3H5)2]2[Mg(C3H5)4], which contains both a cationic cluster Grignard and a tetraorganomagnesiate dianion, are reported.

Graphical abstract: The cationic cluster Grignard [{MgCl(thf)2}3(μ3-C3H5)2]+

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Article information


Submitted
13 Feb 2006
Accepted
31 Mar 2006
First published
11 Apr 2006

Chem. Commun., 2006, 2039-2041
Article type
Communication

The cationic cluster Grignard [{MgCl(thf)2}33-C3H5)2]+

R. A. Layfield, T. H. Bullock, F. García, S. M. Humphrey and P. Schüler, Chem. Commun., 2006, 2039
DOI: 10.1039/B602059C

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