Issue 19, 2006
From the journal:

Chemical Communications

13C NMR spectroscopic study of scandium dimetallofullerene, Sc2@C84vs. Sc2C2@C82

Yuko Iiduka,a   Takatsugu Wakahara,a   Koji Nakajima,a   Takahiro Tsuchiya,a   Tsukasa Nakahodo,a   Yutaka Maeda,b   Takeshi Akasaka,*a   Naomi Mizorogic  and  Shigeru Nagasec  

* Corresponding authors

a Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Japan
E-mail: akasaka@tara.tsukuba.ac.jp
Fax: (+81) 298-53-6409
Tel: (+81) 298-53-6409

b Department of Chemistry, Tokyo Gakugei University, Koganei, Japan

c Department of Theoretical Molecular Science, Institute for Molecular Science, Okazaki, Japan

Abstract

Although Sc2C84 has been widely believed to have the form Sc2@C84, the present 13C NMR study reveals that it is a scandium carbide metallofullerene, Sc2C2@C82, which has a C82(C3v) cage.

Graphical abstract: 13C NMR spectroscopic study of scandium dimetallofullerene, Sc2@C84vs. Sc2C2@C82

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Article information

DOI
https://doi.org/10.1039/B601738J
Article type
Communication
Submitted
06 Feb 2006
Accepted
24 Mar 2006
First published
06 Apr 2006

Chem. Commun., 2006, 2057-2059

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13C NMR spectroscopic study of scandium dimetallofullerene, Sc2@C84vs. Sc2C2@C82

Y. Iiduka, T. Wakahara, K. Nakajima, T. Tsuchiya, T. Nakahodo, Y. Maeda, T. Akasaka, N. Mizorogi and S. Nagase, Chem. Commun., 2006, 2057 DOI: 10.1039/B601738J

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