Issue 18, 2006
From the journal:

Chemical Communications

A new method for the conversion of allyl alcohol into π-allyl species promoted by nucleophilic interaction with a CO ligand†

Christian Dubs,a   Toshiki Yamamoto,a   Akiko Inagakia  and  Munetaka Akita*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, R1-27 4259 Nagatsuta, Midori-ku, Yokohama, Japan
E-mail: makita@res.titech.ac.jp
Fax: +81-45-924-5230

Abstract

Upon treatment with an iridium carbonyl complex, [(PN)Ir(CO)2]+, allyl alcohol can be smoothly converted into π-allyliridium species at ambient temperature via nucleophilic interaction of the alcohol with a CO ligand followed by C(allyl)–O bond cleavage in the resultant protonated allyloxycarbonyl intermediate.

Graphical abstract: A new method for the conversion of allyl alcohol into π-allyl species promoted by nucleophilic interaction with a CO ligand

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Article information

DOI
https://doi.org/10.1039/B601143H
Article type
Communication
Submitted
24 Jan 2006
Accepted
13 Mar 2006
First published
23 Mar 2006

Chem. Commun., 2006, 1962-1964

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A new method for the conversion of allyl alcohol into π-allyl species promoted by nucleophilic interaction with a CO ligand

C. Dubs, T. Yamamoto, A. Inagaki and M. Akita, Chem. Commun., 2006, 1962 DOI: 10.1039/B601143H

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