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Issue 16, 2006
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Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion

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Abstract

Reaction of LAl[η2-(CSiMe3)2] (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) with carbon monoxide and tert-butyl isocyanide afforded unique AlC3 aluminacyclobutenes via insertion into one of the aluminium–carbon bonds.

Graphical abstract: Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion

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Supplementary files

Article information


Submitted
23 Jan 2006
Accepted
03 Mar 2006
First published
15 Mar 2006

Chem. Commun., 2006, 1763-1765
Article type
Communication

Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion

X. Li, C. Ni, H. Song and C. Cui, Chem. Commun., 2006, 1763
DOI: 10.1039/B601056C

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