Issue 6, 2006
From the journal:

Chemical Communications

Highly enantioselective Pd-catalyzed allylic alkylation using new chiral ferrocenylphosphinoimidazolidine ligands

Myung-Jong Jin,*a   Vijay B. Takale,a   M. S. Sarkara  and  Young-Mok Kima  

* Corresponding authors

a School of Chemical Science and Engineering, Inha University, Inchon, South Korea
E-mail: mjjin@inha.ac.kr
Fax: +82-32-860-7469
Tel: +82-32-860-7469

Abstract

New ferrocenylphosphinoimidazolidines containing central chirality and planar chirality were found to act as highly effective chiral ligands in Pd-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate.

Graphical abstract: Highly enantioselective Pd-catalyzed allylic alkylation using new chiral ferrocenylphosphinoimidazolidine ligands

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Article information

DOI
https://doi.org/10.1039/B515283F
Article type
Communication
Submitted
27 Oct 2005
Accepted
22 Dec 2005
First published
06 Jan 2006

Chem. Commun., 2006, 663-664

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Highly enantioselective Pd-catalyzed allylic alkylation using new chiral ferrocenylphosphinoimidazolidine ligands

M. Jin, V. B. Takale, M. S. Sarkar and Y. Kim, Chem. Commun., 2006, 663 DOI: 10.1039/B515283F

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