The structure of lithium garnets: cation disorder and clustering in a new family of fast Li+ conductors

Edmund J. Cussen

doi:10.1039/B514640B

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The structure of lithium garnets: cation disorder and clustering in a new family of fast Li⁺ conductors†

Edmund J. Cussen^a

Author affiliations

^a The School of Chemistry, The University of Nottingham, Nottingham, UK
E-mail: Edmund.Cussen@Nottingham.ac.uk
Fax: +44 115 951 3563
Tel: +44 115 951 3503

Abstract

The structure of the fast lithium-ion conducting garnets Li₅La₃M₂O₁₂ (M = Ta, Nb) reveals Li⁺ on both tetrahedral and octahedral sites and suggests that the latter are responsible for the observed Li⁺ mobility via a clustering mechanism.

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Supplementary files

Full details of the synthetic methods, lattice energy calculations, crystal structures and Rietveld refinements PDF (1331K)

Article information

DOI: https://doi.org/10.1039/B514640B
Article type: Communication
Submitted: 17 Oct 2005
Accepted: 02 Nov 2005
First published: 25 Nov 2005

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Chem. Commun., 2006, 412-413

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The structure of lithium garnets: cation disorder and clustering in a new family of fast Li⁺ conductors

E. J. Cussen, Chem. Commun., 2006, 412 DOI: 10.1039/B514640B

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