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Issue 3, 2006
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Silylzincation of carbon–carbon multiple bonds revisited

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Abstract

The first investigation of the copper-catalyzed silylzincation of alkynes as well as a diene and styrene using bis(triorganosilyl) zinc reagents led to the development of an efficient procedure and the disclosure of an unexpected bissilylation and unforeseen regioselectivity.

Graphical abstract: Silylzincation of carbon–carbon multiple bonds revisited

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Article information


Submitted
23 Sep 2005
Accepted
28 Oct 2005
First published
22 Nov 2005

Chem. Commun., 2006, 311-313
Article type
Communication

Silylzincation of carbon–carbon multiple bonds revisited

G. Auer and M. Oestreich, Chem. Commun., 2006, 311
DOI: 10.1039/B513528A

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