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Issue 4, 2006
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Syntheses and structures of new diaryl lead(ii) compounds PbR2 (1, R = 2,4,6-triphenylphenyl; 2, R = 2,6-bis(1′-naphthyl)phenyl)

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Abstract

Reaction of RLi with lead(II) bromide affords the diaryl lead(II) compounds PbR2 (R1 = 2,4,6-triphenylphenyl, 1; R2 = 2,6-bis(1′-naphthyl)phenyl, 2), which have monomeric, carbene-like structures with bent two-coordinate Pb(II) centers.

Graphical abstract: Syntheses and structures of new diaryl lead(ii) compounds PbR2 (1, R = 2,4,6-triphenylphenyl; 2, R = 2,6-bis(1′-naphthyl)phenyl)

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Publication details

The article was received on 20 Sep 2005, accepted on 20 Oct 2005 and first published on 06 Dec 2005


Article type: Communication
DOI: 10.1039/B513401C
Chem. Commun., 2006, 403-405

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    Syntheses and structures of new diaryl lead(II) compounds PbR2 (1, R = 2,4,6-triphenylphenyl; 2, R = 2,6-bis(1′-naphthyl)phenyl)

    X. Yang, Y. Wang, P. Wei, B. Quillian and G. H. Robinson, Chem. Commun., 2006, 403
    DOI: 10.1039/B513401C

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