Issue 2, 2006

Porphyrin–carborane organometallic assemblies based on 1, 2-dicarba-closo-dodecaborane (12) ligands

Abstract

The assembly of soluble, air-stable, supramolecular structures {(Zn-TPyP)[Cp*Ir{S2C2(B10H10)}]4(THF)2} (2), {(Cu-TPyP)[Cp*Ir{S2C2(B10H10)}]4(THF)2} (3) and {(Zn-TPyP)[Cp*Ir{S2C2(B10H10)}]2·6(CHCl3)}n (4), based on metal-containing moieties [Cp*Ir{S2C2(B10H10)}] (1) bridged by nitrogen-based organic spacers, are described.

Graphical abstract: Porphyrin–carborane organometallic assemblies based on 1, 2-dicarba-closo-dodecaborane (12) ligands

Supplementary files

Article information

Article type
Communication
Submitted
02 Sep 2005
Accepted
25 Oct 2005
First published
18 Nov 2005

Chem. Commun., 2006, 162-164

Porphyrincarborane organometallic assemblies based on 1, 2-dicarba-closo-dodecaborane (12) ligands

J. Wang, C. Ren, L. Weng and G. Jin, Chem. Commun., 2006, 162 DOI: 10.1039/B512416F

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