Issue 5, 2006
From the journal:

Chemical Communications

Mechanistic studies of an unusual epoxide-forming elimination of a β-hydroxyalkyl rhodium porphyrin

Yuan-Zhang Han,a   Melanie S. Sanford,b   Michael D. Englanda  and  John T. Groves*a  

* Corresponding authors

a Department of Chemistry, Princeton University, Princeton, NJ 08544
E-mail: jtgroves@princeton.edu
Fax: +1 609-258-0348
Tel: +1 609-258-3593

b Current address, Department of Chemistry, University of Michigan, Ann Arbor, MI 48109

Abstract

A new and remarkably facile sp3-C–O bond forming reaction of β-hydroxyalkyl Rh porphyrins to form epoxides has been discovered and its mechanism investigated.

Graphical abstract: Mechanistic studies of an unusual epoxide-forming elimination of a β-hydroxyalkyl rhodium porphyrin

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Article information

DOI
https://doi.org/10.1039/B511974J
Article type
Communication
Submitted
22 Aug 2005
Accepted
16 Nov 2005
First published
15 Dec 2005

Chem. Commun., 2006, 549-551

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Mechanistic studies of an unusual epoxide-forming elimination of a β-hydroxyalkyl rhodium porphyrin

Y. Han, M. S. Sanford, M. D. England and J. T. Groves, Chem. Commun., 2006, 549 DOI: 10.1039/B511974J

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