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We report a simple and efficient technique for the covalent immobilisation of a tris(2,2′-bipyridyl)ruthenium(II) derivative suitable for both chemiluminescence and electrochemiluminescence detection.

Graphical abstract: Solid-supported chemiluminescence and electrogenerated chemiluminescence based on a tris(2,2′-bipyridyl)ruthenium(ii) derivative

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