Issue 2, 2006
From the journal:

Chemical Communications

A highly selective synthesis of 3-hydroxy-2-methylpropionamide involving a one-pot tandem hydroformylation–hydrogenation sequence†

Luis García,a   Carmen Claver,a   Montserrat Diéguez*a  and  Anna M. Masdeu-Bultó*a  

* Corresponding authors

a Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Campus Sescelades, c/Marcel·lí Domingo, s/n, Tarragona, Spain
E-mail: montserrat.dieguez@urv.net, annamaria.masdeu@urv.net
Fax: (+34) 977559563
Tel: (+34) 977558779

Abstract

3-Hydroxy-2-methylpropionamide, an important intermediate in the synthesis of methyl methacrylate, has been obtained with excellent conversion and high selectivity from acrylamide by a tandem hydroformylation–hydrogenation sequence catalysed by Rh/PPh3 and Raney Ni, respectively.

Graphical abstract: A highly selective synthesis of 3-hydroxy-2-methylpropionamide involving a one-pot tandem hydroformylation–hydrogenation sequence

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Article information

DOI
https://doi.org/10.1039/B510813F
Article type
Communication
Submitted
29 Jul 2005
Accepted
11 Oct 2005
First published
16 Nov 2005

Chem. Commun., 2006, 191-193

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A highly selective synthesis of 3-hydroxy-2-methylpropionamide involving a one-pot tandem hydroformylation–hydrogenation sequence

L. García, C. Claver, M. Diéguez and A. M. Masdeu-Bultó, Chem. Commun., 2006, 191 DOI: 10.1039/B510813F

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