Fast supercritical fluid chromatography hydrocarbon group-type separations of diesel fuels using packed and monolithic columns

Abstract

Two approaches for decreasing diesel hydrocarbon group-type separation times by normal phase supercritical fluid chromatography (SFC) are compared. Short (10–15 cm) columns with small 3 µm diameter packing are compared with monolithic Chromolith bare silica columns under high carbon dioxide flow rates approaching 5 ml min⁻¹. Elution times are reduced up to 13-fold on a 10 cm Chromolith column and 7-fold on the short packed columns compared with conventional length columns run at typical flow rates. Short packed columns, with their higher surface area and retention characteristics, offer higher resolutions compared with Chromolith columns. Diesel samples are separated into saturates, mono-, di-, tri-, and polyaromatics in as little as 2 min on a 10 cm packed silica column. Diesel group-type results on a 15 cm titania–silica coupled column compare favorably with results from longer columns.