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Issue 22, 2006
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σ-Chelation-directed C–H functionalizations using Pd(ii) and Cu(ii) catalysts: regioselectivity, stereoselectivity and catalytic turnover

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Abstract

Recent progress in σ-chelation directed C–H functionalization from the authors' group is described to illustrate the challenges and opportunities in the development of synthetically-useful catalytic reactions involving C–H activation as the key step. Emphasis is placed on strategies for developing catalysis under mild conditions and controlling regio- and stereoselectivity.

Graphical abstract: σ-Chelation-directed C–H functionalizations using Pd(ii) and Cu(ii) catalysts: regioselectivity, stereoselectivity and catalytic turnover

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Article information


Submitted
01 Aug 2006
Accepted
25 Sep 2006
First published
16 Oct 2006

Org. Biomol. Chem., 2006,4, 4041-4047
Article type
Emerging Area

σ-Chelation-directed C–H functionalizations using Pd(II) and Cu(II) catalysts: regioselectivity, stereoselectivity and catalytic turnover

J. Yu, R. Giri and X. Chen, Org. Biomol. Chem., 2006, 4, 4041
DOI: 10.1039/B611094K

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