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Issue 18, 2006
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A cross-coupling strategy for the synthesis of dimetallic assemblies containing mixed bipyridine–terpyridine bridging ligands: luminescence and energy transfer properties

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Abstract

Tris-bidentate complexes of the form [Ir(N^C)2(N^N)]+ and [Ru(N^N)3]2+ incorporating a boronic acid substituent (N^C = 2-phenylpyridyl, N^N = a 2,2′-bipyridyl ligand), are cross-coupled with bromo-substituted bis-terpyridyl ruthenium and iridium complexes to generate heterometallic assemblies comprising bpy-ϕn-tpy bridges; they display efficient energy transfer from Ir(III) to Ru(II).

Graphical abstract: A cross-coupling strategy for the synthesis of dimetallic assemblies containing mixed bipyridine–terpyridine bridging ligands: luminescence and energy transfer properties

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Supplementary files

Article information


Submitted
10 Feb 2006
Accepted
09 Mar 2006
First published
24 Mar 2006

Dalton Trans., 2006, 2172-2174
Article type
Communication

A cross-coupling strategy for the synthesis of dimetallic assemblies containing mixed bipyridine–terpyridine bridging ligands: luminescence and energy transfer properties

K. J. Arm and J. A. G. Williams, Dalton Trans., 2006, 2172
DOI: 10.1039/B602022D

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