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Issue 9, 2006
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Coordination bonds and strong hydrogen bonds giving a framework material based on a 4- and 8-connected net in [Ca[Co(en)(oxalato)2]2]n

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Abstract

[Ca[Co(ethylenediamine)(oxalato)2]2]n·4H2O gives a 3D-net based on Ca(oxalato)4 8-connected nodes and Co(en)(oxalato)2 4-connected nodes resulting in a compound that retains its structure and 19% void volume even after residual solvent has been evacuated under vacuum at 160 °C.

Graphical abstract: Coordination bonds and strong hydrogen bonds giving a framework material based on a 4- and 8-connected net in [Ca[Co(en)(oxalato)2]2]n

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Article information


Submitted
24 Apr 2006
Accepted
04 Aug 2006
First published
21 Aug 2006

CrystEngComm, 2006,8, 666-669
Article type
Communication

Coordination bonds and strong hydrogen bonds giving a framework material based on a 4- and 8-connected net in [Ca[Co(en)(oxalato)2]2]n

C. Borel, M. Håkansson and L. Öhrström, CrystEngComm, 2006, 8, 666
DOI: 10.1039/B605762D

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