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Issue 38, 2006
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Syntheses, structures, and magnetic characterization of dicyanometalate(ii) building blocks: [NEt4][(Tp*)MII(CN)2] [MII = Cr, Co, Ni; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate]

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Abstract

The syntheses and structures of three dicyanometalate(II) complexes, [NEt4][(Tp*)MII(CN)2nMeCN·½Et2O (MII = Cr, 1, n = ½; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and ½ complexes, respectively.

Graphical abstract: Syntheses, structures, and magnetic characterization of dicyanometalate(ii) building blocks: [NEt4][(Tp*)MII(CN)2] [MII = Cr, Co, Ni; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate]

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Article information


Submitted
12 Jun 2006
Accepted
21 Jul 2006
First published
21 Aug 2006

Chem. Commun., 2006, 4036-4038
Article type
Communication

Syntheses, structures, and magnetic characterization of dicyanometalate(II) building blocks: [NEt4][(Tp*)MII(CN)2] [MII = Cr, Co, Ni; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate]

D. Li, C. Ruschman, S. Parkin, R. Clérac and S. M. Holmes, Chem. Commun., 2006, 4036
DOI: 10.1039/B608297A

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