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Issue 32, 2006
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Phosphine–olefinligands: a facile dehydrogenative route to catalytically active rhodium complexes

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Abstract

Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine–olefin complexes, some of which are catalytically active for 1,4-additions.

Graphical abstract: Phosphine–olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes

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Article information


Submitted
08 Jun 2006
Accepted
04 Jul 2006
First published
21 Jul 2006

Chem. Commun., 2006, 3408-3410
Article type
Communication

Phosphine–olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes

T. M. Douglas, J. L. Nôtre, S. K. Brayshaw, C. G. Frost and A. S. Weller, Chem. Commun., 2006, 3408
DOI: 10.1039/B608129K

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