Issue 41, 2006
From the journal:

Chemical Communications

Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid†

Ana Galet,a   M. Carmen Muñoza  and  José Antonio Real*b  

* Corresponding authors

a Departament de Física Aplicada, Universitat Politécnica de València, Camino de Vera s/n, Valencia, Spain
E-mail: mcmunoz@fis.upv.es

b Instituto de Ciencia Molecular/Departamento de Química Inorgànica, Universitat de València, Edificio de Institutos de Paterna, P O Box 22085, València, Spain
E-mail: jose.a.real@uv.es
Tel: 34 963544856

Abstract

Here we report the synthesis and characterisation of a polymer made up of a system of parallel 2-D grids of Fe(II) ions linked by [Au(CN)2]− bridges and its transformation into a new system of three interpenetrated 3-D coordination open frameworks with the NbO topology. Reversibility of this crystal-to-crystal transformation is evidenced by X-ray crystallographic data and from their spin crossover properties.

Graphical abstract: Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid

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Article information

DOI
https://doi.org/10.1039/B606434E
Article type
Communication
Submitted
08 May 2006
Accepted
08 Aug 2006
First published
06 Sep 2006

Chem. Commun., 2006, 4321-4323

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Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid

A. Galet, M. C. Muñoz and J. A. Real, Chem. Commun., 2006, 4321 DOI: 10.1039/B606434E

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