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Issue 27, 2006
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Reversible lithium insertion and copper extrusion in layered oxysulfides

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Abstract

All of the copper in the layered oxysulfides Sr2MnO2Cu1.5S2 and Sr2MnO2Cu3.5S3 may be extruded as the element and the copper ions replaced quasi-reversibly by lithium ions in reductive topotactic ion exchange reactions; dramatic changes in magnetic properties result.

Graphical abstract: Reversible lithium insertion and copper extrusion in layered oxysulfides

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Article information


Submitted
10 Apr 2006
Accepted
10 May 2006
First published
06 Jun 2006

Chem. Commun., 2006, 2869-2871
Article type
Communication

Reversible lithium insertion and copper extrusion in layered oxysulfides

O. J. Rutt, G. R. Williams and S. J. Clarke, Chem. Commun., 2006, 2869
DOI: 10.1039/B605105G

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