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Issue 16, 2006
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An iron(iii) phosphonate cluster containing a nonanuclear ring

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Abstract

This communication reports the first example of cyclic ferric clusters with an odd number of iron atoms capped by phosphonate ligands, namely, [Fe9(μ-OH)7(μ-O)2(O3PC6H9)8(py)12]. The magnetic studies support a S = 1/2 ground state with an exchange coupling constant of about J ≈ −30 K.

Graphical abstract: An iron(iii) phosphonate cluster containing a nonanuclear ring

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Article information


Submitted
18 Jan 2006
Accepted
27 Feb 2006
First published
13 Mar 2006

Chem. Commun., 2006, 1745-1747
Article type
Communication

An iron(III) phosphonate cluster containing a nonanuclear ring

H. Yao, J. Wang, Y. Ma, O. Waldmann, W. Du, Y. Song, Y. Li, L. Zheng, S. Decurtins and X. Xin, Chem. Commun., 2006, 1745
DOI: 10.1039/B600763E

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