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Issue 16, 2006
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An iron(iii) phosphonate cluster containing a nonanuclear ring†

Hong-Chang Yao,a   Jun-Jie Wang,a   Yun-Sheng Ma,a   Oliver Waldmann,*b   Wen-Xin Du,c   You Song,a   Yi-Zhi Li,a   Li-Min Zheng,*a   Silvio Decurtins*b  and  Xin-Quan Xina  
Author affiliations

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, P. R. China
E-mail: lmzheng@nju.edu.cn

b Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, Bern, Switzerland
E-mail: oliver.waldmann@iac.unibe.ch, silvio.decurtins@iac.unibe.ch

c State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, P. R. China

Abstract

This communication reports the first example of cyclic ferric clusters with an odd number of iron atoms capped by phosphonate ligands, namely, [Fe9(μ-OH)7(μ-O)2(O3PC6H9)8(py)12]. The magnetic studies support a S = 1/2 ground state with an exchange coupling constant of about J ≈ −30 K.

Graphical abstract: An iron(iii) phosphonate cluster containing a nonanuclear ring

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Article information

Submitted
18 Jan 2006
Accepted
27 Feb 2006
First published
13 Mar 2006
Chem. Commun., 2006, 1745-1747
Article type
Communication
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An iron(III) phosphonate cluster containing a nonanuclear ring

H. Yao, J. Wang, Y. Ma, O. Waldmann, W. Du, Y. Song, Y. Li, L. Zheng, S. Decurtins and X. Xin, Chem. Commun., 2006, 1745
DOI: 10.1039/B600763E

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