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Issue 13, 2006
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Bromoiodinanes with an I(iii)–Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents

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Abstract

Bromoiodinanes—conveniently and directly prepared from iodobenzenecarbinols and N-bromosuccinimide, and characterised for the first time crystallographically—act as electrophilic bromine donors.

Graphical abstract: Bromoiodinanes with an I(iii)–Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents

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Article information


Submitted
12 Jan 2006
Accepted
06 Feb 2006
First published
22 Feb 2006

Chem. Commun., 2006, 1442-1444
Article type
Communication

Bromoiodinanes with an I(III)–Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents

D. C. Braddock, G. Cansell, S. A. Hermitage and A. J. P. White, Chem. Commun., 2006, 1442
DOI: 10.1039/B600455E

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