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Issue 15, 2006
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A new Co(ii) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with TC ≈ 68 K

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Abstract

Reaction of Co(II) chloride with the sodium salt of 2-mercaptonicotinic acid in water at 200 °C results in the formation of Co4(2-mna)4(H2O), which orders as a canted antiferromagnet at 68 K.

Graphical abstract: A new Co(ii) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with TC ≈ 68 K

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Article information


Submitted
13 Jan 2006
Accepted
23 Feb 2006
First published
08 Mar 2006

Chem. Commun., 2006, 1607-1609
Article type
Communication

A new Co(II) coordination solid with mixed oxygen, carboxylate, pyridine and thiolate donors exhibiting canted antiferromagnetism with TC ≈ 68 K

S. M. Humphrey, A. Alberola, C. J. G. García and P. T. Wood, Chem. Commun., 2006, 1607
DOI: 10.1039/B600347H

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