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Issue 27, 2006
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Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}

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Abstract

The ionic character of a set of two redox linkages and strong, directional halogen bonding at the organic–inorganic interface compromise to produce two materials sharing a common two-dimensional net, eventually extended in a third dimension, although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.

Graphical abstract: Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}

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Supplementary files

Article information


Submitted
06 Jan 2006
Accepted
26 May 2006
First published
08 Jun 2006

Chem. Commun., 2006, 2878-2880
Article type
Communication

Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}

A. Ranganathan, A. El-Ghayoury, C. Mézière, E. Harté, R. Clérac and P. Batail, Chem. Commun., 2006, 2878
DOI: 10.1039/B600159A

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