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Issue 22, 2006
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Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation

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Abstract

The oxidation state of the phenol-substituted porphyrin TDtBHPP is coupled with its structure so that its 2-electron oxidation leads to a coplanarization of the molecule and a substantial stabilization of its surface self-assembled structures adsorbed at metal substrates.

Graphical abstract: Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation

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Supplementary files

Article information


Submitted
13 Dec 2005
Accepted
07 Feb 2006
First published
27 Feb 2006

Chem. Commun., 2006, 2320-2322
Article type
Communication

Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation

J. P. Hill, Y. Wakayama, W. Schmitt, T. Tsuruoka, T. Nakanishi, M. L. Zandler, A. L. McCarty, F. D'Souza, L. R. Milgrom and K. Ariga, Chem. Commun., 2006, 2320
DOI: 10.1039/B517668A

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