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Issue 6, 2006
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One-pot cross-metathesis/tandem carbonyl ylide formation–intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester

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Abstract

Dicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation–intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation.

Graphical abstract: One-pot cross-metathesis/tandem carbonyl ylide formation–intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester

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Publication details

The article was received on 10 Nov 2005, accepted on 11 Jan 2006 and first published on 18 Jan 2006


Article type: Communication
DOI: 10.1039/B515943A
Chem. Commun., 2006, 627-628

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    One-pot cross-metathesis/tandem carbonyl ylide formation–intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester

    D. M. Hodgson, D. Angrish and A. H. Labande, Chem. Commun., 2006, 627
    DOI: 10.1039/B515943A

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