Issue 12, 2006
From the journal:

Chemical Communications

Bridging ligand planarity as a route to long-lived, near infrared emitting dinuclear ruthenium(ii) complexes

Matthew I. J. Polson,†a   Frédérique Loiseau,b   Sebastiano Campagna*b  and  Garry S. Hanan*a  

* Corresponding authors

a Département de Chimie, Université de Montréal, 2900 Edouard-Montpetit, Montréal, Québec, Canada
E-mail: garry.hanan@umontreal.ca
Fax: +1 514 343 2468
Tel: +1 514 343 7056

b Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Via Sperone 31, Messina, Italy
E-mail: campagna@unime.it
Fax: +39 090 393 756
Tel: +39 090 676 5737

Abstract

The dinuclear ruthenium complex of a large, planar bis-tridentate bridging ligand has been prepared; to the best of our knowledge, this species is the near IR-emitting Ru(II) complex exhibiting the longest-lived emission and highest quantum yield reported so far, due to the dramatic reduction in its radiationless decay rate constant.

Graphical abstract: Bridging ligand planarity as a route to long-lived, near infrared emitting dinuclear ruthenium(ii) complexes

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Article information

DOI
https://doi.org/10.1039/B515493F
Article type
Communication
Submitted
31 Oct 2005
Accepted
31 Jan 2006
First published
10 Feb 2006

Chem. Commun., 2006, 1301-1303

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Bridging ligand planarity as a route to long-lived, near infrared emitting dinuclear ruthenium(II) complexes

M. I. J. Polson, F. Loiseau, S. Campagna and G. S. Hanan, Chem. Commun., 2006, 1301 DOI: 10.1039/B515493F

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