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Issue 42, 2006
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BF3·OEt2 and TMSOTf: A synergistic combination of Lewis acids

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Abstract

The combination of BF3·OEt2 and TMSOTf gives BF2OTf·OEt2, which is a more powerful Lewis acid than its components and especially effective in CH3CN solvent; the complex formed has been characterised by 1H, 19F, 11B and 31P (using Et3PO as an additive) NMR spectroscopy.

Graphical abstract: BF3·OEt2 and TMSOTf: A synergistic combination of Lewis acids

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Supplementary files

Article information


Submitted
07 Aug 2006
Accepted
21 Aug 2006
First published
14 Sep 2006

Chem. Commun., 2006, 4434-4436
Article type
Communication

BF3·OEt2 and TMSOTf: A synergistic combination of Lewis acids

E. L. Myers, C. P. Butts and V. K. Aggarwal, Chem. Commun., 2006, 4434
DOI: 10.1039/B611333H

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