Issue 34, 2006
From the journal:

Chemical Communications

Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes†

Eric S. Schmidtmanna  and  Martin Oestreich*a  

* Corresponding authors

a Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstraße 40, Germany
E-mail: martin.oestreich@uni-muenster.de
Fax: +49 (0)251 83-36501
Tel: +49 (0)251 83-33271

Abstract

Isotopic desymmetrisation, as well as (stereo)chemical correlation, has illuminated significant aspects of the σ–π–σ mechanism of copper-catalysed allylic substitution reactions: an enantiospecific and regioselective access to α-chiral silanes is presented.

Graphical abstract: Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes

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Article information

DOI
https://doi.org/10.1039/B606589A
Article type
Communication
Submitted
09 May 2006
Accepted
04 Jul 2006
First published
28 Jul 2006

Chem. Commun., 2006, 3643-3645

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Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes

E. S. Schmidtmann and M. Oestreich, Chem. Commun., 2006, 3643 DOI: 10.1039/B606589A

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