Issue 3, 2005
From the journal:

Organic & Biomolecular Chemistry

Subtle factors are important: radical formation and transmetallation in reactions of butyl cuprates with cyclohexyl iodide†

Steven H. Bertz,*a   Jason Human,b   Craig A. Ogle*b  and  Paul Seagleb  

* Corresponding authors

a Complexity Study Center, Mendham, USA
E-mail: sbertz@complexitystudycenter.org

b University of North Carolina–Charlotte, Charlotte, USA
E-mail: cogle@email.uncc.edu

Abstract

The reactions of Bu2CuLi·LiI and Bu2CuLi·LiCN with cyclohexyl iodide are critically dependent upon subtle factors such as the surface properties of the reaction vessel, nature of the solvent still and lot of ‘ultrapure’ copper salt in addition to major effects such as the Li counterion.

Graphical abstract: Subtle factors are important: radical formation and transmetallation in reactions of butyl cuprates with cyclohexyl iodide

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Article information

DOI
https://doi.org/10.1039/B416612D
Article type
Communication
Submitted
28 Oct 2004
Accepted
06 Dec 2004
First published
10 Jan 2005

Org. Biomol. Chem., 2005,3, 392-394

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Subtle factors are important: radical formation and transmetallation in reactions of butyl cuprates with cyclohexyl iodide

S. H. Bertz, J. Human, C. A. Ogle and P. Seagle, Org. Biomol. Chem., 2005, 3, 392 DOI: 10.1039/B416612D

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