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Issue 2, 2005
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Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (±)-aspidospermidine

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Abstract

Azide 14, available through the title cross-coupling process, has been converted, via the ring-fused aziridine 15, into the alkaloid aspidospermidine.

Graphical abstract: Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (±)-aspidospermidine

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Article information


Submitted
19 Oct 2004
Accepted
15 Nov 2004
First published
07 Dec 2004

Org. Biomol. Chem., 2005,3, 213-215
Article type
Communication

Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (±)-aspidospermidine

M. G. Banwell and D. W. Lupton, Org. Biomol. Chem., 2005, 3, 213
DOI: 10.1039/B415977B

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