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Selective oxidations of (i) phenols and condensed aromatics to quinones and (ii) alkynes to α,β-acetylenic ketones mediated by supported iron phthalocyanine complexes exhibit very different mechanistic features as evidenced by 18O labelling and kinetic isotope effect studies.

Graphical abstract: Mechanistic diversity of the selective oxidations mediated by supported iron phthalocyanine complexes

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