Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(v) compound†
Abstract
Single crystal X-ray structures of two 2-iodylbenzenesulfonamides reveal a combination of intra- and intermolecular I⋯O interactions leading to a typical hexacoordinated and a unique heptacoordinated iodine(V) center.