Issue 9, 2005
From the journal:

New Journal of Chemistry

Substituent effects and mechanism elucidation of enantioselective sulfoxidation catalyzed by vanadium Schiff base complexes

Qingle Zeng,*a   Heqing Wang,a   Wen Weng,b   Wenshi Lin,b   Yuxing Gao,a   Xiantong Huanga  and  Yufen Zhao*a  

* Corresponding authors

a Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, Xiamen University, Xiamen, China
E-mail: qlzeng@xmu.edu.cn; yfzhao@xmu.edu.cn
Fax: +86-592-2185780
Tel: +86-592-2185780

b Department of Chemistry, Zhangzhou Teachers College, Zhangzhou, China

Abstract

The effects of substituents of the Schiff base ligands on oxovanadium-catalyzed enantioselective sulfoxidation were first systematically studied, and a rational mechanism of enantioselective sulfoxidation based on our experimental data and the reported data is proposed.

Graphical abstract: Substituent effects and mechanism elucidation of enantioselective sulfoxidation catalyzed by vanadium Schiff base complexes

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Article information

DOI
https://doi.org/10.1039/B505237H
Article type
Letter
Submitted
15 Apr 2005
Accepted
12 Jul 2005
First published
21 Jul 2005

New J. Chem., 2005,29, 1125-1127

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Substituent effects and mechanism elucidation of enantioselective sulfoxidation catalyzed by vanadium Schiff base complexes

Q. Zeng, H. Wang, W. Weng, W. Lin, Y. Gao, X. Huang and Y. Zhao, New J. Chem., 2005, 29, 1125 DOI: 10.1039/B505237H

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