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Issue 12, 2005
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Esterification of carboxylic acids by tributyl borate under solvent- and catalyst-free conditions

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Abstract

A new method for esterification of mono- and dicarboxylic acids by tributyl borate has been reported. The esterification reactions have been cleanly carried out in the absence of any solvent under catalyst-free conditions. Boric acid is the only side product, which precipitates during the reaction and can be re-used in the production of tributyl borate. Important mono- and dibutylesters, which have found wide applications as plasticizers and ester base lubricants, were prepared by this manner.

Graphical abstract: Esterification of carboxylic acids by tributyl borate under solvent- and catalyst-free conditions

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Publication details

The article was received on 18 Jul 2005, accepted on 27 Sep 2005 and first published on 07 Oct 2005


Article type: Paper
DOI: 10.1039/B510164F
Green Chem., 2005,7, 870-873

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    Esterification of carboxylic acids by tributyl borate under solvent- and catalyst-free conditions

    Y. Mansoori, F. S. Tataroglu and M. Sadaghian, Green Chem., 2005, 7, 870
    DOI: 10.1039/B510164F

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