Enantiomeric interpenetrating 3D nets with chiral silver helicates

Yan Bai; Chun-ying Duan; Ping Cai; Dong-bin Dang; Qing-jin Meng

doi:10.1039/B506596H

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Enantiomeric interpenetrating 3D nets with chiral silver helicates†

Yan Bai,^a Chun-ying Duan,*^a Ping Cai,^a Dong-bin Dang^a and Qing-jin Meng^a

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* Corresponding authors

^a Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P. R. China
E-mail: duancy@nju.edu.cn

Abstract

A new enantiomeric interpenetrating 3D nets with chiral helical coordination silver(I) polymer was achieved via self-assembly using the new ligand modular approach, in which the special helical conformation of the ligand provided the opportunity to translate chirality from one metal center to others.

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Supplementary files

Fig. S1: A view of the double interpenetrating nets of enantiomeric forms of the chiral 3D networks. Hydrogen atoms, anions and solvent molecules were omitted for clarity (a); Schematic representation of potential interpenetrating structures resulting from two topologically equivalent 3D nets of enantiomeric networks (b). PDF (286K)

Article information

DOI: https://doi.org/10.1039/B506596H
Article type: Communication
Submitted: 10 May 2005
Accepted: 04 Jul 2005
First published: 18 Jul 2005

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Dalton Trans., 2005, 2678-2680

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Enantiomeric interpenetrating 3D nets with chiral silver helicates

Y. Bai, C. Duan, P. Cai, D. Dang and Q. Meng, Dalton Trans., 2005, 2678 DOI: 10.1039/B506596H

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Dalton Transactions

Enantiomeric interpenetrating 3D nets with chiral silver helicates†

Abstract

Supplementary files

Article information

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Enantiomeric interpenetrating 3D nets with chiral silver helicates

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