Donor effect on supramolecular structures of silver(I) perchlorate complexes of macrocycles with O2S2X (XS, O and NH) donor sets

Il Yoon; Joobeom Seo; Ji-Eun Lee; Mi Ryoung Song; So Young Lee; Kyu Seong Choi; Ok-Sang Jung; Ki-Min Park; Shim Sung Lee

doi:10.1039/B506438D

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Donor effect on supramolecular structures of silver(i) perchlorate complexes of macrocycles with O₂S₂X (XS, O and NH) donor sets†‡

Il Yoon,^a Joobeom Seo,^a Ji-Eun Lee,^a Mi Ryoung Song,^a So Young Lee,^a Kyu Seong Choi,^b Ok-Sang Jung,^c Ki-Min Park^a and Shim Sung Lee*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Chinju, S. Korea
E-mail: sslee@gsnu.ac.kr

^b Department of Chemistry, Kyungnam University, Masan, S. Korea.

^c Department of Chemistry, Pusan National University, Pusan, S. Korea.

Abstract

By virtue of simple one donor variations of O₂S₂X-donor macrocycles (L¹: X [double bond, length as m-dash] S, L²: XO and L³: XNH) towards silver(I) perchlorates, four supramolecular complexes (1–3) with different topologies have been isolated; L¹ afforded solvent- and anion-free sandwich complex (1), otherwise L² and L³ gave the dimeric (2a), 1-D polymeric (2b), and tetrameric bowl-type (3) complexes with solvent or anion coordination.

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Article information

DOI: https://doi.org/10.1039/B506438D
Article type: Communication
Submitted: 09 May 2005
Accepted: 01 Jun 2005
First published: 10 Jun 2005

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Dalton Trans., 2005, 2352-2354

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Donor effect on supramolecular structures of silver(I) perchlorate complexes of macrocycles with O₂S₂X (XS, O and NH) donor sets

I. Yoon, J. Seo, J. Lee, M. R. Song, S. Y. Lee, K. S. Choi, O. Jung, K. Park and S. S. Lee, Dalton Trans., 2005, 2352 DOI: 10.1039/B506438D

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Dalton Transactions