Issue 16, 2005
From the journal:

Dalton Transactions

N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes

Robin B. Bedford,*a   Michael Betham,a   Michael E. Blake,b   Robert M. Frost,b   Peter N. Horton,c   Michael B. Hursthousec  and  Rosa-María López-Nicolásd  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: r.bedford@bristol.ac.uk

b Department of Chemistry, University of Exeter, Exeter, UK

c EPSRC National Crystallography Service, Department of Chemistry, University of Southampton, Highfield Road, Southampton, UK

d Grupo de Quimica Organometalica, Departamento de Quimica Inorganica, Facultad de Quimica, Universidad de Murcia, Apdo. 4021, Murcia, Spain

Abstract

Carbene adducts of orthopalladated triarylphosphite complexes have been synthesised and characterised. The structures of three of these complexes were determined by single-crystal X-ray analysis. The complexes are active in the Suzuki coupling of a range of aryl bromide substrates.

Graphical abstract: N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes

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Article information

DOI
https://doi.org/10.1039/B506286A
Article type
Paper
Submitted
05 May 2005
Accepted
30 Jun 2005
First published
18 Jul 2005

Dalton Trans., 2005, 2774-2779

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N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes

R. B. Bedford, M. Betham, M. E. Blake, R. M. Frost, P. N. Horton, M. B. Hursthouse and R. López-Nicolás, Dalton Trans., 2005, 2774 DOI: 10.1039/B506286A

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