Issue 47, 2005
From the journal:

Chemical Communications

Selective site controlled nucleophilic attacks in 5-membered ring phosphateesters: unusual C–O vs. common P–O bond cleavage†

Nissan Ashkenazi,*a   Sanjio S. Zade,b   Yoffi Segall,a   Yishai Kartona  and  Michael Bendikov*b  

* Corresponding authors

a Department of Organic Chemistry, IIBR-Israel Institute for Biological Research, PO Box 19, Ness-Ziona, Israel
E-mail: nissan.ashkenazi@iibr.gov.il
Fax: +972-8-9381548
Tel: +972-8-9381454

b Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel
E-mail: michael.bendikov@weizmann.ac.il
Fax: +972-8-9344142
Tel: +972-8-9346028

Abstract

Clean endocyclic C–O bond cleavage has been achieved in the reactions of 5-membered phosphate triesters with various nucleophiles.

Graphical abstract: Selective site controlled nucleophilic attacks in 5-membered ring phosphate esters: unusual C–O vs. common P–O bond cleavage

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Article information

DOI
https://doi.org/10.1039/B512117E
Article type
Communication
Submitted
26 Aug 2005
Accepted
28 Sep 2005
First published
31 Oct 2005

Chem. Commun., 2005, 5879-5881

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Selective site controlled nucleophilic attacks in 5-membered ring phosphate esters: unusual C–O vs. common P–O bond cleavage

N. Ashkenazi, S. S. Zade, Y. Segall, Y. Karton and M. Bendikov, Chem. Commun., 2005, 5879 DOI: 10.1039/B512117E

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