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Issue 47, 2005
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[LnIIAlIII2(alkyl)8]x: donor addition instead of donor-induced cleavage

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Abstract

(SmAl2Me8)x and (SmAl2Et8)x are obtained via a silylamide elimination reaction from Sm[N(SiMe3)2]2(THF)2 and excess AlR3 (R = Me, Et); (LnAl2Et8)x (Ln = Sm, Yb) react with THF, pyridine, and 1,10-phenanthroline to form the first donor adducts of homoleptic peralkylated Ln–Al heterobimetallic complexes.

Graphical abstract: [LnIIAlIII2(alkyl)8]x: donor addition instead of donor-induced cleavage

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Supplementary files

Article information


Submitted
25 Aug 2005
Accepted
21 Sep 2005
First published
21 Oct 2005

Chem. Commun., 2005, 5922-5924
Article type
Communication

[LnIIAlIII2(alkyl)8]x: donor addition instead of donor-induced cleavage

M. G. Schrems, H. M. Dietrich, K. W. Törnroos and R. Anwander, Chem. Commun., 2005, 5922
DOI: 10.1039/B512047K

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