Issue 46, 2005
From the journal:

Chemical Communications

Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocenecatalysts by electrospray ionization mass spectrometry

Fabio di Lena,a   Esther Quintanillaa  and  Peter Chen*a  

* Corresponding authors

a Laboratorium für Organische Chemie, ETH Zürich, Wolfgang-Pauli-Strasse 10, CH-8093 Zürich, Switzerland
E-mail: chen@org.chem.ethz.ch
Fax: +41-44-632-1280
Tel: +41-44-632-2898

Abstract

Electrospray ionization mass spectrometry (ESI-MS) of MAO-activated metallocene-catalyzed polymerizations quenched with carbodiimides provides a method for the determination of rate constants in Ziegler–Natta polymerizations.

Graphical abstract: Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry

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Article information

DOI
https://doi.org/10.1039/B511997A
Article type
Communication
Submitted
24 Aug 2005
Accepted
30 Sep 2005
First published
21 Oct 2005

Chem. Commun., 2005, 5757-5759

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Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry

F. di Lena, E. Quintanilla and P. Chen, Chem. Commun., 2005, 5757 DOI: 10.1039/B511997A

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