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Issue 41, 2005
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Stereospecific change in conformation upon complexation of an exoditopic tetraamide host with a bis(ammonium) guest: chiral recognition and strong CD signaling

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Abstract

Upon complexation of a rectangular-shaped achiral macrocyclic host with chiral guests, twisting deformation occurs to induce exciton-type bisignated CD, whereas a chiral rectangular host undergoes a similar structural change only with the matching enantiomer of a chiral guest.

Graphical abstract: Stereospecific change in conformation upon complexation of an exoditopic tetraamide host with a bis(ammonium) guest: chiral recognition and strong CD signaling

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Article information


Submitted
20 Jul 2005
Accepted
31 Aug 2005
First published
13 Sep 2005

Chem. Commun., 2005, 5154-5156
Article type
Communication

Stereospecific change in conformation upon complexation of an exoditopic tetraamide host with a bis(ammonium) guest: chiral recognition and strong CD signaling

R. Katoono, H. Kawai, K. Fujiwara and T. Suzuki, Chem. Commun., 2005, 5154
DOI: 10.1039/B510134D

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