The first stable 2-germadisilaallene was synthesized by the reduction of a 2 ∶ 1 mixture of a stable dialkylsilylene and dichlorogermylene–dioxane complex with KC8; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state.
T. Iwamoto, T. Abe, C. Kabuto and M. Kira, Chem. Commun., 2005, 5190 DOI: 10.1039/B509878E
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