Issue 37, 2005
From the journal:

Chemical Communications

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes†

Xile Hu,a   Brandi M. Cossairt,a   Bruce S. Brunschwig,a   Nathan S. Lewis*a  and  Jonas C. Peters*a  

* Corresponding authors

a Division of Chemistry and Chemical Engineering, Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA
E-mail: jpeters@caltech.edu
Fax: +1 6265774088
Tel: +1 6263954036

Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as −0.28 V vs. SCE.

Graphical abstract: Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

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Article information

DOI
https://doi.org/10.1039/B509188H
Article type
Communication
Submitted
28 Jun 2005
Accepted
29 Jul 2005
First published
23 Aug 2005

Chem. Commun., 2005, 4723-4725

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Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

X. Hu, B. M. Cossairt, B. S. Brunschwig, N. S. Lewis and J. C. Peters, Chem. Commun., 2005, 4723 DOI: 10.1039/B509188H

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