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Issue 38, 2005
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Direction of topological isomers of silver(i) coordination polymers induced by solvent, and selective anion-exchange of a class of PtS-type host frameworks

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Abstract

The construction of two types of coordination polymers with closely related 4-connected topologies [PtS and lvt (42.84)] were achieved based on a well-designed bent dipyrazine linker, and the topological differences only result from the stereochemistry of silver(I) coordination sphere with the same coordination donors. Selective anion-exchange functions of the series of PtS-type coordination networks containing different counter anions (from small BF4 to very large SbF6) were identified.

Graphical abstract: Direction of topological isomers of silver(i) coordination polymers induced by solvent, and selective anion-exchange of a class of PtS-type host frameworks

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Article information


Submitted
16 Jun 2005
Accepted
29 Jul 2005
First published
02 Sep 2005

Chem. Commun., 2005, 4836-4838
Article type
Communication

Direction of topological isomers of silver(I) coordination polymers induced by solvent, and selective anion-exchange of a class of PtS-type host frameworks

M. Du, X. Zhao, J. Guo and S. R. Batten, Chem. Commun., 2005, 4836
DOI: 10.1039/B508479B

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