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Issue 32, 2005
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Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances

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Abstract

Reaction of diastereomerically pure phosphinoselenoic acid salts with oxalyl chloride leads to enantiomerically pure P-chiral phosphinoselenoic chlorides with inversion of configuration at phosphorus; one of these chlorides is converted to a phosphinoselenothioic acid salt with a high degree of enantioselectivity.

Graphical abstract: Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances

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Article information


Submitted
01 Jun 2005
Accepted
23 Jun 2005
First published
13 Jul 2005

Chem. Commun., 2005, 4077-4079
Article type
Communication

Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances

T. Kimura and T. Murai, Chem. Commun., 2005, 4077
DOI: 10.1039/B507755A

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